Skip to main content

Main navigation

  • About ITEFI
  • Research
  • Formación y empleo
  • OpenLab
  • Servicios científico técnicos
  • Staff Directory

Graphene oxide as sensitive layer in Love-wave surface acoustic wave sensors for the detection of chemical warfare agent simulants

graphene oxide
acoustic wave gas sensor
love wave sensors
chemical warfare agent simulants
I. Sayago, D. Matatagui, M.J. Fernández, J.L. Fontecha, I. Jurewicz, R.Garriga and E. Muñoz
Talanta, Volume 148, 1 February 2016, Pages 393–400
http://dx.doi.org/10.1016/j.talanta.2015.10.069

A Love-wave device with graphene oxide (GO) as sensitive layer has been developed for the detection of chemical warfare agent (CWA) simulants. Sensitive films were fabricated by airbrushing GO dispersions onto Love-wave devices. The resulting Love-wave sensors detected very low CWA simulant concentrations in synthetic air at room temperature (as low as 0.2 ppm for dimethyl-methylphosphonate, DMMP, a simulant of sarin nerve gas, and 0.75 ppm for dipropylene glycol monomethyl ether, DPGME, a simulant of nitrogen mustard). High responses to DMMP and DPGME were obtained with sensitivities of 3087 and 760 Hz/ppm respectively. Very low limit of detection (LOD) values (9 and 40 ppb for DMMP and DPGME, respectively) were calculated from the achieved experimental data. The sensor exhibited outstanding sensitivity, good linearity and repeatability to all simulants tested. The detection mechanism is here explained in terms of hydrogen bonding formation between the tested CWA simulants and GO.

Acknowledgments

This work has been supported by the Spanish Science and Innovation Ministry under project TEC2013-C6-4-R, and by EPSRC. The authors wish to thank Dr. C. Cané and Dr. I. Gràcia from the Centro Nacional de Microelectrónica IMB-CSIC for providing the micro-machined SAW substrates.

Grupo de I+D en Sensores
SENSAVAN
NOySI
Acoustics and Non Destructive Evaluation (DAEND)
  • Environmental Acoustics (GAA)
  • G Carma: Materials Characterization by Non Destructive Evaluation
  • ULAB, Ultrasounds for Liquid Analysis and Bioengineering
Information and Communication Technologies (TIC)
  • Cybersecurity and Privacy Protection Research Group (GiCP)
  • Research group on Cryptology and Information Security (GiCSI)
    • Quantum Communications Laboratory (LCQE)
  • Multichannel Ultrasonic Signal Processing Group (MUSP)
Sensors and Ultrasonic Systems (DSSU)
  • Ultrasonic Systems and Technologies (USTG)
  • Nanosensors and Smart Systems (NoySi)
  • Ultrasonic Resonators for cavitation and micromanipulation (RESULT)
  • Advanced Sensor Technology (SENSAVAN)
  • Quantum Electronics (QE)
Laboratorios
  • Laboratorio de Acústica
  • Laboratorio de Metrología Ultrasónica Médica (LMUM)
  • Laboratorio de Comunicaciones Cuánticas
  • Laboratory for International Collaboration in Advanced Biophotonics Imaging

Instituto de Tecnologías Físicas y de la Información Leonardo Torres Quevedo  - ITEFI
C/ Serrano, 144. 28006 - Madrid • Tel.: (+34) 91 561 88 06  Contacto  •  Intranet
EDIFICIO PARCIALMENTE ACCESIBLE POR PERSONAS CON MOVILIDAD REDUCIDA